Boiler efficiency is mainly depended on the amount of losses in the system. In high capacity pulverized coal fired boilers the total losses account to about 12 to 14%. Roughly 50% of the losses are governed by fuel properties like hydrogen in fuel, moisture in fuel and ambient air conditions. The other 50% losses are carbon loss and dry gas loss. The best efficiency in the boiler can be achieved if the losses are kept to the minimum. Since 50% of the losses are dependent on the fuel and ambient condition, the best efficiency can be achieved by properly tuning the other 50%, i.e. mainly carbon loss and dry gas loss.
Volatile matter in coal refers to the components of coal, except for moisture, which are liberated at high temperature in the absence of air. This is usually a mixture of short- and long-chain hydrocarbons, aromatic hydrocarbons and some sulfur. Volatile matter also evaluate the adsorption application of an activated carbon. The volatile matter of coal is determined under rigidly controlled standards. In Australian and British laboratories this involves heating the coal sample to 900 ± 5 °C (1650 ±10 °F) for 7 min. Also as the rank of coal increases the volatile matter decreases (AMK).